Growth Position and Chirality Control of Single-Walled Carbon Nanotubes

We propose a novel technique to grow the single-walled carbon nanotubes (SWNTs) with specific chirality at the desired position using free electron laser (FEL) irradiation during growth and surface treatment. As a result, only the semiconducting SWNTs grew at the area between triangle electrodes, where the ozone treatment was done to be hydrophilic when an alcohol chemical vapor deposition (ACCVD) process was carried out with the 800 nm FEL irradiation. Although the number of possible chiral index is 22 in the SWNTs grown without the FEL irradiation, the number is much reduced to be 8 by the FEL. key words: single-walled carbon nanotube, ACCVD, chirality, free electron laser, Raman spectra